Rare Earth Doped Silica Nanoparticles via Thermolysis of a Single Source Metallasilsesquioxane Precursor

نویسندگان

  • Gemma-Louise Davies
  • John O’Brien
  • Yurii K. Gun’ko
چکیده

Rare earth metal doped silica nanoparticles have significant advantages over traditional organic dyes and quantum dots. Silsesquioxanes are promising precursors in the production of silica nanoparticles by thermolysis, due to their structural similarities with silica materials. This manuscript describes the production of a new Eu3+-based metallasilsesquioxane species and its use as a single source precursor in the thermolytic production of luminescent rare earth metal doped silica nanoparticles with characteristic emission in the visible region of the spectrum.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Erbium-doped nanoparticles in silica-based optical fibres

Developing of new rare-earth (RE)-doped optical fibres for power amplifiers and lasers requires continuous improvements in the fibre spectroscopic properties (like shape and width of the gain curve, optical quantum efficiency, resistance to spectral hole burning and photodarkening,...). Silica glass as a host material for fibres has proved to be very attractive. However some potential applicati...

متن کامل

Erbium emission properties in nanostructured fibers.

A new route was recently proposed to modify some spectroscopic properties of rare-earth ions in silica-based fibers. We had shown the incorporation of erbium ions in amorphous dielectric nanoparticles, grown in fiber preforms. Here we present the achieved stabilization of nanometric erbium-doped dielectric nanoparticles within the core of silica fibers. We present the nanoparticle dimensional c...

متن کامل

Luminescent Ions in Silica-Based Optical Fibers

We present some of our research activities dedicated to doped silica-based optical fibers, aiming at understanding the spectral properties of luminescent ions, such as rare-earth and transition metal elements. The influence of the local environment on dopants is extensively studied: energy transfer mechanisms between rare-earth ions, control of the valence state of Chromium ions, effect of the ...

متن کامل

Wet-chemical synthesis of different bismuth telluride nanoparticles using metal organic precursors - single source vs. dual source approach.

Thermolysis of the single source precursor (Et2Bi)2Te in DIPB at 80 °C yielded phase-pure Bi4Te3 nanoparticles, while mixtures of Bi4Te3 and elemental Bi were formed at higher temperatures. In contrast, cubic Bi2Te particles were obtained by thermal decomposition of Et2BiTeEt in DIPB. Moreover, a dual source approach (hot injection method) using the reaction of Te(SiEt3)2 and Bi(NMe2)3 was appl...

متن کامل

Rare earth doped fiber lasers and amplifiers pdf

Also the optical fiber amplifiers FAs that amplify weak signals such as the. Rare-Earth-Doped Fiber Lasers and Amplifiers, Michael J.F.Chapter 2. Optical and Electronic Properties of Rare Earth Ions in Glasses William J Miniscalco Abstract-HiRes PDF 2316 KB-PDF wlinks 2330 KB.amplifier materials in the system of rare-earth doped glasses are presented. rare-earth-doped ram concept manual pdf fib...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره 7  شماره 

صفحات  -

تاریخ انتشار 2017